Interpretation of Carbon-13 NMR Spectra

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Contents
PREFACE
1 BASIC PRINCIPLES
	1.1 History of Carbon-13 Nuclear Magnetic Resonance
	1.2 Relaxation and Nuclear Overhauser Effect
	1.3 Instrumental Requirements
2 THE SPECTRAL PARAIVIETERS
	2.1 The Chemical Shift
	2.2 Spin-spin Coupling
3 EXPERIMENTAL TECHNIQUES FOR SPECTRAL ASSIGNMENT
	3.1 Summary of Methods
	3.2 Proton-decoupling Techniques
	3.3 Polarization Transfer and Related Experiments
	3.4 Selective Excitation
	3.5 Two-dimensional Experiments
	3.6 Carbon-Carbon Connectivity Experiments
	3.7 Lanthanide Shift Reagents
	3.8 Chemical Shift Comparison
	3.9 Isotope Effects
	3.10 Solid State 13C-NMR
4 NUCLEAR SPIN RELAXATION
	4.1 Correlation and Spectral Density Function
	4.2 Dipole-Dipole Relaxation
	4.3 Other Relaxation Mechanisms
	4.4 Anisotropic Rotational Diffusion
	4.5 Experimental Techniques for the Measurement of T1 and theNuclear Overhauser Effect (NOE)
	4.6 Temperature and Concentration Dependence of the Rotational Correlation Time.
	4.7 Relative Contributions from Individual Relaxation Mechanisms
5 APPLICATIONS
	5.1 Introduction
	5.2 Structure Elucidation of Organic Molecules
	5.3 Dynamic Processes, Conformational Analysis
	5.4 Two-dimensional Techniques for the Elucidation of Exchange Networks
	5.5 Rotamer equilibria
	5.6 Macromolecules
	5.7 Solid-state 13C-NMR Applications
	5:8 Mechanistic Studies
	5.9 Spin-Lattice Relaxation and Nuclear Overhauser Studies
	5.10 Quantitative Analysis
APPENDIX: SOLUTIONS TO PROBLEMS
COMPOUND INDEX
SUBJECT INDEX